Iron in north-east Pacific waters

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Gordon, R. M., Martin, J. H., & Knauer, G. A. (1982). Iron in north-east Pacific waters. Nature, 299(5884), 611-612. doi:10.1038/299611a0
Metadata
TitleIron in north-east Pacific waters
AuthorsM. Gordon, H. Martin, A. Knauer
AbstractAlthough Fe is an element of great biological 1 and geochemical 2 importance, little is known about its distribution in the sea. The reasons for this are: (1) contamination is extremely difficult to avoid during sampling and laboratory procedures, not only because of man's wide use of this element, but also because it is fourth most abundant element in the Earth's crust (5.63%) 3; (2) the chemistry of Fe is very complex, and its form (or forms) in seawater is poorly known, hence whether one preconcentration technique will work for existing species is questionable. Iron also appears to be very insoluble 4 in oxygenated ocean water, and most (90%) 5 precipitates out in association with dissolved organics during estuarine mixing processes 5-8. Indeed, some argue that truly dissolved Fe does not exist in seawater and that the fraction found in filtrates is totally colloidal 9. We have been attempting oceanic dissolved Fe measurements for the past four years and report here three vertical Fe profiles (Fig. 1) that have the following features in common: Fe is severely depleted (0.15-0.30 nmol kg -1) in surface waters; Fe maxima (up to 2.6 nmol kg -1) occur in association with oxygen minima; and, Fe levels appear to vary little in mid-depth waters (0.5-1.0 nmol kg -1).
JournalNature
Date1982
Start page611
End page612
ISSN00280836
NoteCited By (since 1996):33

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