Search results

Title: In situ chemical mapping of dissolved iron and manganese in hydrothermal plumes,
Description: Hydrothermal vents along mid-ocean ridges are an important source of elements such as lithium, silicon, manganese and iron to the world's oceans. The venting produces both episodic and steady-state hydrothermal plumes with unique thermochemical signatures in the mid-water column. The particulate phases in these plumes (predominantly iron oxides and hydroxides) also scavenge phosphorus, vanadium, arsenic, lead, polonium and several rare-earth elements from sea water. Thus, on a global scale, hydrothermal plumes are both a source for some elements and a sink for others. Ultimately, the particulate metals precipitated from plumes form extensive regions of metalliferous sediments over the crests and flanks of mid-ocean ridges. Although the metalliferous sediment coverage is vast and well documented, only a tiny fraction of the vents responsible for these sediments have been located (Fig. 1a). To date, both the number and location of hydrothermal vents and the detailed distribution of chemical constituents within the resultant plumes are poorly understood because of under-sampling of the mid-ocean ridges and the overlying waters. Here we present the results of high-resolution mapping of the chemical and thermal characteristics of hydrothermal plumes in near real time using a novel submersible chemical analyser (Scanner) and a conductivity/temperature/depth/transmissometer instrument package (CTDT). We show that the kinetics of iron oxidation in the plume can be used to constrain estimates of the plume's age, and that variation in the ratio of manganese content to excess heat can be explained by the mixing of several different vent fluids., Cited By (since 1996):31, CODEN: NATUA, ,
Author: Coale, Chin, Massoth, Johnson, Baker
Date: 1991-01-01T00:00:00Z

Title: Cobalt and copper distributions in the waters of Santa Monica Basin, California,
Description: The trace metals cobalt and copper are removed from the oceans interior by scavenging on to particle surfaces, but the mechanisms for removal of these two metals are probably quite different. Cobalt appears to be scavenged by manganese oxide particles, whereas organic compounds are the main carrier phase for copper. Remobilization of these metals in marine sediments therefore proceeds by different pathways. The differences in the pathways of remobilization are accentuated in oxygen-deficient environments: manganese oxide reduction is accelerated at low oxygen levels and organic carbon is preserved. Cobalt fluxes from sediments underlying oxygen-deficient waters should be enhanced and copper fluxes reduced. We report here measurements of the cobalt and copper distributions in the waters of an oxygen-deficient marine basin in the Southern California Bight. Cobalt concentrations near the bottom are raised four times above the background level, whereas copper concentrations show no increase. These measurements confirm features of existing models for the oceanic cycles of these metals., Cited By (since 1996):18, Oceanography, CODEN: NATUA, ,
Author: Johnson, Stout, Berelson, Sakamoto-Arnold
Date: 1988-01-01T00:00:00Z

Title: Chemical and biological interactions in the Rose Garden hydrothermal vent field, Galapagos spreading center,
Description: The concentrations of a suite of redox reactive chemicals were measured in the Rose Garden hydrothermal vent field of the Galapagos spreading center. Sulfide, silicate, oxygen and temperature distributions were measured in situ with a submersible chemical analyser. In addition, 15 chemical species were measured in discrete samples. Variability in the slope of the temperature-silicate plots indicates that heat is lost from these relatively low temperatures (<15°C) solutions by conduction to the solid phase. Consumption of oxygen, sulfide and nitrate from the hydrothermal solution as it flows past the vent animals is apparent from the distributions measured in situ and in the discrete samples. The fraction of sulfide and nitrate removed from the solution by consumption appears to have increased between 1979-1985. Sulfide and oxygen appear to be consumed under different conditions: sulfide is removed primarily from the warmest solutions, and oxygen is consumed only from the cold seawater. This separation may be driven primarily by the increased gradients of each chemical under these conditions. There is no evidence for the consumption of significant amounts of manganese(II) by the vent organisms. The analysis of other data sets from this vent field indicate no significant consumption of methane by the vent organisms, as well. © 1988., Cited By (since 1996):103, Oceanography, ,
Author: Johnson, Childress, Hessler, Sakamoto-Arnold, Beehler
Date: 1988-01-01T00:00:00Z

Title: The tail of the Storegga Slide: Insights from the geochemistry and sedimentology of the Norwegian Basin deposits
Description: Deposits within the floor of the Norwegian Basin were sampled to characterize the deposition from the Storegga Slide, the largest known Holocene-aged continental margin slope failure complex. A 29 to 67 cm thick veneer of variable-coloured, finely layered Holocene sediment caps a homogeneous, extremely well-sorted, poorly consolidated, very fine-grained, grey-coloured sediment section that is >20 m thick on the basin floor. This homogeneous unit is interpreted to represent the uppermost deposits generated by a gravity flow associated with the last major Storegga Slide event. Sediments analogous to the inferred source material of the slide deposits were collected from upslope on the Norwegian Margin. Sediments sampled within the basin are distinguishable from the purported source sediments, suggesting that size sorting has significantly altered this material along its flow path. Moreover, the very fine grain size (3·1 ± 0·3 μm) suggests that the >20 m thick homogeneous unit which was sampled settled from suspension after the turbulent flow was over. Although the turbulent phase of the gravity flow that moved material out into the basin may have been brief (days), significantly more time (years) is required for turbid sediments to settle and dewater and for the new sea floor to be colonized with a normal benthonic fauna. Pore water sulphate concentrations within the uppermost 20 m of the event deposit are higher than those normally found in sea water. Apparently the impact of microbial sulphate reduction over the last ca 8·1 cal ka bp since the re-deposition of these sediments has not been adequate to regenerate a typical sulphate gradient of decreasing concentration with sub-bottom depth. This observation suggests low rates of microbial reactions, which may be attributed to the refractory carbon composition in these re-deposited sediments. © 2010 The Authors. Journal compilation © 2010 International Association of Sedimentologists., Cited By (since 1996):1, Rocks & Cores
Author: Paull, Ussler III, Holbrook, Hill, Haflidason, Winters, Lorenson, Aiello, Johnson, Lundsten
Date: 2010-01-01T00:00:00Z

Title: Benthic manganese fluxes along the Oregon-California continental shelf and slope
Description: Here we examine the factors that influence the manganese (Mn) benthic flux from eastern North Pacific marine sediments, with a primary emphasis on continental shelf locations off Oregon and California and studies that involve the use of in situ benthic chambers. Typical shelf-to-shallow margin (<~350m) sites have benthic Mn efflux rates that average ~8±5μmolm-2d-1. In contrast, for the Eel River continental shelf region the benthic Mn efflux can be an order of magnitude higher than other shelf settings with benthic effluxes exceeding ~50μmolm-2d-1. Based on prior work and some new results, continental margin and slope sites (350-~4000m) have benthic Mn efflux rates that average ~1±1μmolm-2d-1. The combination of the benthic flux and Mn solid-phase data, indicate that for the continental shelf off the Umpqua and Eel Rivers, approximately 15±10% of the total Mn that is delivered to the seafloor is remobilized. The compiled data set shows that the benthic Mn efflux co-varies with the organic carbon oxidation rate with a Mn to organic carbon oxidation (Cox) ratio of ~0.8mmol Mn mol-1. Although this ratio can be as high as ~5 for some Eel River sites, the generally close correspondence between Mn and organic carbon implies that the organic carbon oxidation rate exerts some primary control over the rate of the Mn efflux. The amount of organic carbon oxidized by Mn-oxides, however, represents a small fraction (i.e., generally <1%) of the total organic carbon oxidized in these seafloor sediments. © 2012 Elsevier Ltd., Cited By (since 1996):5, Oceanography, CODEN: CSHRD
Author: McManus, Berelson, Severmann, Johnson, Hammond, Roy, Coale
Date: 2012-01-01T00:00:00Z

Title: Stray light correction of the marine optical system,
Description: The Marine Optical System is a spectrograph-based sensor used on the Marine Optical Buoy for the vicarious calibration of ocean color satellite sensors. It is also deployed from ships in instruments used to develop bio-optical algorithms that relate the optical properties of the ocean to its biological content. In this work, an algorithm is applied to correct the response of the Marine Optical System for scattered, or improperly imaged, light in the system. The algorithm, based on the measured response of the system to a series of monochromatic excitation sources, reduces the effects of scattered light on the measured source by one to two orders of magnitude. Implications for the vicarious calibration of satellite ocean color sensors and the development of bio-optical algorithms are described. The algorithm is a one-dimensional point spread correction algorithm, generally applicable to nonimaging sensors, but can in principle be extended to higher dimensions for imaging systems. © 2009 American Meteorological Society., Cited By (since 1996):6, Oceanography, CODEN: JAOTE, , , Downloaded from: journals.ametsoc.org/doi/pdf/10.../2008JTECHO597.1 (16 June 2014).
Author: Feinholz, Flora, Yarbrough, Lykke, Brown, Johnson, Clark
Date: 2009-01-01T00:00:00Z

Title: Spectrophotometric determination of dissolved manganese in natural waters with 1-(2-pyridylazo)-2-naphthol: Application to analysis in situ in hydrothermal plumes,
Description: A spectrophotometric method using the complexing reagent 1-(2-pyridylazo)-2-naphthol (PAN) was developed for the determination of dissolved manganese in seawater. A detection limit of approximately 22 nM was obtained when the analyses were performed in situ with a submersible chemical analyzer (Scanner). Color formation was rapid (less than 1 s), which permitted the technique to be used in flow injection and continuous flow systems. An investigation of possible interferences revealed that the only significant interferent to manganese determinations in seawater (hydrothermal plumes) was iron. The iron-specific chelating agent desferrioxamine B was used to mask this interference. Temperature and pressure did not adversely affect the sensitivity of the technique, which made it amenable to applications in situ to depths of 3000 m. This method was tested by measuring dissolved manganese concentrations in situ in submarine hydrothermal plumes using a Scanner. Scanner deployments over the Juan de Fuca Ridge produced the first near real time analyses of manganese from a hydrothermal plume environment. Estuarine samples have also been successfully analyzed in the laboratory and the results confirmed by an independent method. © 1992., Cited By (since 1996):22, Oceanography, CODEN: MRCHB, ,
Author: Chin, Johnson, Coale
Date: 1992-01-01T00:00:00Z

Title: The behaviour of iron and other trace elements during the IronEx-I and PlumEx experiments in the Equatorial Pacific,
Description: Dissolved (< 0.4 μm) and particulate (0.4-5 μm and > 5 μm, leachable and refractory) trace elements were measured during the IronEx I and PlumEx experiments in October and November 1993 near the Galapagos Islands. Iron was measured in the enriched patch and at control stations over a 9 day period following fertilization. The dissolved iron was initially depleted at a rate that gave an iron half-life of 28-40 h. The loss rate gradually decreased, and dissolved iron concentrations did not decrease below about 0.25 nmol kg-1 throughout the experiment. These results were most consistent with a kinetic model that was second order in iron concentration for the scavenging removal of each iron fraction. Other trace elements measured did not change significantly either in concentration or partitioning during the IronEx I experiment. Biological production tracked iron concentrations over time, which suggests that productivity within the fertilized patch was regulated by the availability of iron. The PlumEx study consisted primarily of two transects, a meridional course to the east of the Galapagos Islands and a zonal section to the west. Surface dissolved iron was very low at all stations except those near the Galapagos Islands. Sections of trace metal and other properties distinctly confirm the upwelling of the Equatorial Undercurrent as it intersects the islands. This upwelling has a great effect on the surface distributions of the trace metals on the west side of the islands. Productivity within the mixed layer of this region is highly correlated with iron and nitrate. West of the islands highest productivity is found at stations with the highest iron. North of the Equatorial front, in nitrate-depleted waters, elevated iron concentrations do not enhance productivity., Cited By (since 1996):58, Oceanography, CODEN: DSROE, ,
Author: Gordon, Johnson, Coale
Date: 1998-01-01T00:00:00Z

Title: The Marine Optical Buoy (MOBY) radiometric calibration and uncertainty budget for ocean color satellite sensor vicarious calibration,
Description: For the past decade, the Marine Optical Buoy (MOBY), an autonomous radiometric buoy stationed in the waters off Lanai, Hawaii, has been the primary in-water oceanic observatory for the vicarious calibration of U. S. satellite ocean color sensors, including the Sea-viewing Wide Field-of-view Sensor (SeaWiFS) and the Moderate Resolution Imaging Spectrometer (MODIS) instruments on the National Aeronautics and Space Administration's (NASA's) Terra and Aqua satellites. The MOBY vicarious calibration of these sensors supports international efforts to develop a global, multi-year time series of consistently calibrated ocean color data products. A critical component of the MOBY program is establishing radiometric traceability to the International System of Units (SI) through standards provided by the U. S. National Institute of Standards and Technology (NIST). A detailed uncertainty budget is a core component of traceable metrology. We present the MOBY uncertainty budget for up-welling radiance and discuss approaches in new instrumentation to reduce the uncertainties in in situ water-leaving radiance measurements., Cited By (since 1996):10, Oceanography, Art. No.: 67441M, CODEN: PSISD, ,
Author: Brown, Flora, Feinholz, Yarbrough, Houlihan, Peters, Yong, Mueller, Johnson, Clark
Date: 2007-01-01T00:00:00Z

Title: The flux of iron from continental shelf sediments,
Description: The flux of dissolved iron from sediments to the water column was measured with flux chambers along the California coast over a five-year period. High fluxes were observed from sediments on the continental shelf. The measured fluxes were an average of 75 times larger than flux values derived from pore-water iron gradients. The iron flux was significantly correlated with the oxidation of organic matter, which allows an extrapolation to the global shelf. The input from shelf sediments is at least as significant as the global input of dissolved iron from aerosols, which has been presumed to be the dominant external iron source. Evidence of this input is seen 100's of kilometers offshore where it can enable the high productivity of broad coastal regions seen in satellite images. Copyright 2004 by the American Geophysical Union., Cited By (since 1996):125, Oceanography, CODEN: GPRLA, ,
Author: Elrod, Berelson, Coale, Johnson
Date: 2004-01-01T00:00:00Z

Title: Radiometric characterization and absolute calibration of the Marine Optical System (MOS) Bench Unit,
Description: The Marine Optical System (MOS) is a dual charge-coupled device (CCD)-based spectrograph system developed for in-water measurements of downwelling solar irradiance E d and upwelling radiance L u. These measurements are currently used in the calibration and validation of satellite ocean color measurement instruments such as the moderate resolution imaging spectroradiometer (MODIS) and the Sea-viewing Wide Field-of view Sensor (SeaWiFS). MOS was designed to be deployed from a ship for single measurements and also integrated into the Marine Optical Buoy (MOBY) for longer time series datasets. Measurements with the two spectrographs in the MOS systems can be compared in the spectral interval from about 580 to 630 nm. In this spectral range, they give different values for L u or E d at a common wavelength. To better understand the origin of this observation and the sources of uncertainty in the calibration of MOBY, an MOS bench unit was developed for detailed radiometric characterization and calibration measurements in a laboratory setting. In the work reported here, a novel calibration approach is described that uses a tunable laser-based, monochromatic, spatially uniform. Lambertian, large area integrating sphere source (ISS). Results are compared with those obtained by a conventional approach using a lamp-illuminated ISS. Differences in the MOS bench unit responsivity between the two calibration approaches were observed and attributed to stray light. A simple correction algorithm was developed for the lamp-illuminated ISS that greatly improves the agreement between the two techniques. Implications for water-leaving radiance measurements by MOS are discussed., Cited By (since 1996):2, CODEN: JAOTE, , , Downloaded from: journals.ametsoc.org/ (13 June 2014).
Author: Habauzit, Brown, Lykke, Johnson, Feinholz, Yarbrough, Clark
Date: 2003-01-01T00:00:00Z

Title: A model of the iron cycle in the ocean,
Description: The IRONEX II in situ fertilization experiment showed decisively that availability of iron limits the growth of phytoplankton in equatorial Pacific surface waters. High-nutrient low-chlorophyll (HNLC) surface waters, potentially iron limited, are also found in the North Pacific and the Southern Ocean. A model of seawater iron geochemistry has been incorporated into a global ocean circulation and carbon cycle model and tuned to match the observed ocean Fe distribution. The model reproduces the observed HNLC areas in the equatorial Pacific and Southern Ocean but predicts nutrient depletion in the North Pacific (a region of high dust fluxes from Asia). The model is based on the idea that the concentrations of organic iron-binding ligands in seawater control the subsurface Fe concentration and predicts that a majority (70-80%) of the global carbon export production can be sustained by upwelling of dissolved iron in seawater rather than by atmospheric deposition. The ocean iron cycle increases the efficiency of iron utilization in the biological pump, buffers new production against interannual fluctuations in iron deposition, and contributes several new intrinsic timescales to the ocean carbon cycle: several hundred years for the ocean iron concentration and perhaps several thousand for the concentration of ligand in the deep sea. Ocean recycling of Fe appears to play a major role in determining the strength of the biological pump in the ocean and the pCO2 of the atmosphere., Cited By (since 1996):117, , , Oceanography
Author: Archer, Johnson
Date: 2000-01-01T00:00:00Z

Title: A time series of benthic flux measurements from Monterey Bay, CA,
Description: In situ incubation chamber measurements of benthic nutrient recycling rates were made on the Monterey Bay shelf at 100m during various years and seasons. Variability in nutrient (Si, PO 4 2+, NH 3, NO 3 -) and trace metal (Mn, Fe (II), Cu) fluxes correlate with variability in the amount of organic carbon oxidized on the sea floor. Patterns of primary productivity show a mid-year maxima, consistent with the timing of increased rates of benthic C org and opal recycling. High rates of C org rain to the shelf promote nitrate consumption at a rate that equals or exceeds ammonia efflux. Low rates of C org rain promote greater efflux of DIN; thus these margin sediments provide a negative feedback to local productivity cycles. The efflux of iron (II) from shelf sediments is sufficient to support > 100% of new production, yet Fe flux is positively correlated with C org recycling which lags the maximum in new production. On account of this time lag, diagenetically recycled Fe is not likely a micro-nutrient trigger of new production, but could serve as a positive feedback. Bio-irrigation rates are seasonally variable by 30% but maximal during the maximum productivity months. © 2003 Elsevier Science Ltd. All rights reserved., Cited By (since 1996):65, CODEN: CSHRD, , , Oceanography
Author: Berelson, McManus, Coale, Johnson, Burdige, Kilgore, Colodner, Chavez, Kudela, Boucher
Date: 2003-01-01T00:00:00Z

Title: Ocean optics protocols for satellite ocean color semsor validation, revision 4, Volume VI: Special topics in ocean protocols and appendices,
Description: , , ,
Author: Mueller, Clark, Kuwahara, Lazin, Brown, Fargion, Yarbrough, Feinholz, Flora, Broenkow, Kim, Johnson, Yuen, Strutton, Dickey, Abbott, Letelier, Lewis, McLean, Chavez, Barnard, Morrison, Subramaniam, Manov, Zheng, Harding Jr., Barnes, Lykke
Date: 2003-01-01T00:00:00Z

Title: Solenoid pumps for flow injection analysis,
Description: Methods employing flow injection analysis (FIA), particularly for in situ seawater techniques, would benefit from reduction in pump size and power requirement, longer maintenance intervals, and the ability to incorporate microprocessor control of each reagent and sample flow stream. In this work, the peristaltic pump of a conventional FIA system was replaced by three solenoid-driven diaphragm pumps with integral Viton check valves, and the system was tested by performing the simple nitrile analysis, which has well-defined FIA performance characteristics. Sixty injections per hour were possible with flow rates of 0.5 mL/min for reagents and sample. The coefficient of variation was 1% for 10μM NO2- concentrations, and the detection limit was less than 0.1μM NO2-. These values match the reported performance for this method using peristaltic pumps., , CODEN: IJCVE, ,
Author: Weeks, Johnson
Date: 1996-01-01T00:00:00Z

Title: Simultaneous measurement of up-welling spectral radiance using a fiber-coupled CCD spectrograph,
Description: Determination of the water-leaving spectral radiance using in-water instrumentation requires measurements of the upwelling spectral radiance (L u) at several depths. If these measurements are separated in time, changes in the measurement conditions result in increased variance in the results. A prototype simultaneous multi-track system was developed to assess the potential reduction in the Type A uncertainty in single set, normalized water-leaving radiance achievable if the data were acquired simultaneously. The prototype system employed a spectrograph and multi-track fiber-coupled CCD-detector; in situ in-water tests were performed with the prototype system fiber-coupled to a small buoy. The experiments demonstrate the utility of multi-channel simultaneous data acquisition for in-water measurement applications. An example of the potential impact for tracking abrupt responsivity changes in satellite ocean color sensors using these types of instruments as well as for the satellite vicarious calibration is given., Cited By (since 1996):1, Oceanography, Art. No.: 66800J, CODEN: PSISD, ,
Author: Yarbrough, Flora, Feinholz, Houlihan, Kim, Brown, Johnson, Voss, Clark
Date: 2007-01-01T00:00:00Z

Title: Morphological, molecular, and in situ behavioral observations of the rare deep-sea anglerfish Chaunacops coloratus (Garman, 1899), order Lophiiformes, in the eastern North Pacific
Description: In situ observations and collections of Chaunacops coloratus (Garman, 1899) from seamounts in the eastern North Pacific Ocean lend new behavioral, morphological and molecular data to an under-sampled, deep-sea group of fishes in the order Lophiiformes. Seven observations were made at Davidson Seamount, 130. km southwest of Monterey, CA, and from the Taney Seamount chain, 290. km west of Moss Landing, CA, from depths ranging from 2313 to 3297. m. Specimens were collected at both locations. Morphometric and meristic analyses were performed to identify individuals to the species level. These observations of C. coloratus provide greater latitude and depth distributions in the eastern North Pacific Ocean than previously known. Detailed habitat information indicated the fish occurred near manganese-encrusted volcanic talus slopes, a highly rugose habitat. Video observations revealed possible ontogenetic color changes in which small fish were blue and large fish were red. Video recorded rapid, vertical swimming as an escape response and maneuvering, or walking, with pectoral and pelvic fins and esca deployment. Phylogenetic analyses used here verify what has been known since Garman first described C. coloratus in 1899, that Chaunax and Chaunacops are closely related; molecular tools complement previous knowledge and genetic information created has been submitted to GenBank for further use by the scientific community. © 2012 Elsevier Ltd.
Author: Lundsten, Johnson, Cailliet, DeVogelaere, Clague
Date: 2012-01-01T00:00:00Z

Title: Phosphorus regeneration in continental margin sediments,
Description: Benthic incubation chambers have been deployed in a variety of geochemical environments along the California Continental Margin. These include both high and low oxygen environments and sites where the rate of organic matter oxidation on the seafloor (Cox) ranges from < 1 mmol m-2 day-1 to more than 7 mmol m-2 day-1 through a depth range of 100-3500 m. This range in the rate of organic matter oxidation along with variations in the concentration of bottom water oxygen allow us to elucidate the diagenetic conditions under which P regeneration may be decoupled from organic matter cycling. Under conditions where bottom water oxygen concentration is low (<50 μM), and the rate of organic matter oxidation is also low (< 1 mmol m-2 day-1), P regeneration may be less than that expected from the decay of organic debris and, in some cases, there is a flux of phosphate into the sediments. At stations where bottom water oxygen is low, and the degradation rate of organic material is greater than 1 mmol m-2 day-1, phosphate may be released at a rate exceeding the production expected from the oxidation of organic matter. At stations having high bottom water oxygen concentrations, rates of organic matter decomposition < ∼7 mmol m-2 day-1, and where benthic irrigation is not significant, P regeneration is consistent with that expected from the decomposition of organic debris. In addition, our data indicate that high benthic iron fluxes are observed in regions exhibiting a decoupling between organic matter and phosphate, whereas low to zero iron fluxes are observed in regions where P regeneration is either consistent with or less than that expected from the decomposition of organic material. These results support previous work suggesting a coupling between iron cycling and phosphate cycling in suboxic environments. Data presented here show that this coupling may result in either preferential phosphate burial or release relative to organic material in suboxic environments. Copyright © 1997 Elsevier Science Ltd., Cited By (since 1996):105, ,
Author: Mcmanus, Berelson, Coale, Johnson, Kilgore
Date: 1997-01-01T00:00:00Z

Title: Determination of subnanomolar levels of iron(II) and total dissolved iron in seawater by flow injection analysis with chemiluminescence detection
Description: A highly sensitive technique for the rapid determination of Fe( I I) and total dlssolved iron in seawater has been developed. The technlque employs flow Injection analysis and chemiluminescence detectlon (FIA-CL). The light Is emitted by the reaction of brilliant sulfoflavin with hydrogen peroxlde and Fe( I I ) in a neutral medlum. A cation-exchange column Is used to preconcentrate the Iron from seawater. The detection limit was 0.45 nmol/L when 4.4 mL of sample was passed through the column. Lower detectlon llmlts are attainable wlth larger sample volumes. The relative standard deviation is 2-5% for concentrations greater than 2.5 nmd/L. A typical analysis can be performed In 5 mln. The technique was determlned to be accurate based on the analysis of the trace metal standard seawater solutions NASS and CASS. Shipboard analyses provided oceanographically consistent profiles for total iron and also revealed some of the first profiles for Fe(I1) in hydrothermal plume samples. A typical profile of 12 samples, together with blanks and standards, can be analyzed In triplicate in 4.5 h.
Author: Elrod, Johnson, Coale

Title: Continuous determination of nitrate concentrations in situ,
Description: A submersible chemical analyser (Scanner) was used to measure nitrate concentrations in situ to depths of nearly 2000 m. Nitrate anomalies with a vertical span of 5 m can be detected at lowering rates up to 40 m min-1. The nitrate concentrations measured in situ are in good agreement with hydrographic data collected by conventional means at the same location. The relative standard deviation of the analyses performed in situ is ±0.79%. The method can be easily extended to most other colorimetric analyses., Cited By (since 1996):9 Oceanography, ,
Author: Johnson, Sakamoto-Arnold, Beehler
Date: 1989-01-01T00:00:00Z

Title: Iron deficiency and phytoplankton growth in the equatorial Pacific,
Description: Several experiments were conducted in the equatorial Pacific at 140°W during the Joint Global Ocean Flux Study, equatorial Pacific, 1992 Time-series I (TS-I, 23 March-9 April). Time-series II (TS-II, 2-20 October) and FeLINE II cruises (10 March-14 April), to investigate the effects of added Fe on phytoplankton communities. Seven series of deckboard iron-enrichment experiments were performed, with levels of added Fe ranging from 0.13 to 1000 nM. Time-course measurements included nutrients, chlorophyll a and HPLC pigments. Results of these experiments showed that subnanomolar (sub-nM) additions of Fe increased net community specific growth rates, with resultant chlorophyll a increases and nutrient decreases. Community growth rates followed Michaelis Menten type kinetics resulting in maximum rates of 0.99 doublings per day and a half-saturation constant of 0.12 nM iron. The dominant group responding to iron enrichment was diatoms., Cited By (since 1996):62, CODEN: DSROE, ,
Author: Fitzwater, Coale, Gordon, Johnson, Ondrusek
Date: 1996-01-01T00:00:00Z

Title: A time series of benthic flux measurements from Monterey Bay, CA,
Description: , , , In situ incubation chamber measurements of benthic nutrient recycling rates were made on the Monterey Bay shelf at 100 m during various years and seasons. Variability in nutrient (Si, PO42+, NH3, NO3−) and trace metal (Mn, Fe (II), Cu) fluxes correlate with variability in the amount of organic carbon oxidized on the sea floor. Patterns of primary productivity show a mid-year maxima, consistent with the timing of increased rates of benthic Corg and opal recycling. High rates of Corg rain to the shelf promote nitrate consumption at a rate that equals or exceeds ammonia efflux. Low rates of Corg rain promote greater efflux of DIN; thus these margin sediments provide a negative feedback to local productivity cycles. The efflux of iron (II) from shelf sediments is sufficient to support >100% of new production, yet Fe flux is positively correlated with Corg recycling which lags the maximum in new production. On account of this time lag, diagenetically recycled Fe is not likely a micro-nutrient trigger of new production, but could serve as a positive feedback. Bio-irrigation rates are seasonally variable by 30% but maximal during the maximum productivity months., ,
Author: Berelson, McManus, Coale, Johnson, Burdige, Kilgore, Colodner, Chavez, Kudela, Boucher
Date: 2003-01-01T00:00:00Z

Title: Larval settlement can explain the adult distribution of Mytilus californianus Conrad but not of M. galloprovincialis Lamarck or M. trossulus Gould in Moss Landing, central California,
Description: We investigated the spatial distribution of adult and newly settled mussels (Mytilus galloprovincialis Lamarck, Mytilus trossulus Gould and Mytilus californianus Conrad) on the shore at Moss Landing, California to test the hypothesis that adult distributions are a result of settlement patterns. Adult M. californianus were most abundant on a wave-exposed rocky jetty and adults of Blue mussels (M. trossulus and M. galloprovincialis) were more abundant inside the protected Moss Landing harbor. Using taxon-specific polymerase chain reactions, we monitored recruitment during continuous 1-2 week intervals on fibrous scrubbing pads for 12 months in 2002-2003. All mussel species settled in greatest numbers on the exposed jetty, and Blue mussels settled in greater numbers there than did M. californianus. Because Blue mussels settled abundantly where their adults were rare, post-settlement mortality appeared to be the strongest influence on adult distribution. In contrast, M. californianus settled mostly in their adult habitat., Cited By (since 1996):13, CODEN: JEMBA, ,
Author: Johnson, Geller
Date: 2006-01-01T00:00:00Z

Title: The flux of iron from continental shelf sediments: A missing source for global budgets
Description: The flux of dissolved iron from sediments to the water column was measured with flux chambers along the California coast over a five-year period. High fluxes were observed from sediments on the continental shelf. The measured fluxes were an average of 75 times larger than flux values derived from pore-water iron gradients. The iron flux was significantly correlated with the oxidation of organic matter, which allows an extrapolation to the global shelf. The input from shelf sediments is at least as significant as the global input of dissolved iron from aerosols, which has been presumed to be the dominant external iron source. Evidence of this input is seen 100’s of kilometers offshore where it can enable the high productivity of broad coastal regions seen in satellite images.
Author: Elrod, Berelson, Coale, Johnson

Title: Organic matter diagenesis in the sediments of the San Pedro Shelf along a transect affected by sewage effluent,
Description: A study was conducted to examine the rate of organic matter degradation within the sediments adjacent to the Whites Point Los Angeles County sewage outfall system on the San Pedro Shelf. Benthic chamber deployments were made at three stations in a transect away from the outfall pipe during three cruise periods (October 1990, February and October 1991). The fluxes of phosphate, silicate and radon-222 showed the most significant difference (factor of 3) between stations proximal and distal to the sewage effluent outfall pipe; the fluxes of nitrate, ammonia, alkalinity and TCO2 showed some gradient (a factor of 1.5-2) and the uptake of oxygen showed no variability between sites. Carbon oxidation in these sediments is driven primarily by net oxygen consumption and secondarily by net sulfate reduction. Net sulfate reduction accounts for about 30% of the carbon oxidation near the outfall pipe and 10-15% at the distal sites. Measurements of radon-222 fluxes and radon emanation rates from sediments indicate that the intensity of bio-irrigation is greater by a factor of 2 at sites away from the outfall pipe, but also shows that bio-irrigation does take place at the site adjacent to the pipe. The total amount of particulate organic carbon (POC) oxidized in the sediments around the outfall is ∼2 × 107 g C/d. An estimate of carbon burial in this region is 4 × 107 g C/d. The outfall system could supply ∼3 × 107 g C/d of which 12-20% is estimated to have been deposited in the region. Hence, effluent-derived POC, although it may be a part of the total organic carbon pool undergoing diagenesis and burial on the sea floor, is not likely the only source of carbon to this system. Primary productivity in the surface ocean could supply 9-13 × 107 g C/d to the sea floor. A balanced carbon budget requires that half the primary production is exported to the sea floor, although this budget does not account for other sources of POC to the region. © 2002 Elsevier Science Ltd. All rights reserved., Cited By (since 1996):13, CODEN: CSHRD, ,
Author: Berelson, Johnson, Coale, Li
Date: 2002-01-01T00:00:00Z

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